Heavy Metals
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In what form is emitted lead?
Lead in the environment arises from both natural and anthropogenic sources. Exposure can occur through drinking water, food, air, soil and dust from old paint containing lead. In the general non-smoking, adult population the major exposure pathway is from food and water. Food, air, water and dust/soil are the major potential exposure pathways for infants and young children. For infants up to 4 or 5 months of age, air, milk formulae and water are the significant sources.
Lead is among the most recycled non-ferrous metals and its secondary production has therefore grown steadily in spite of declining lead prices. Its physical and chemical properties are applied in the manufacturing, construction and chemical industries. It is easily shaped and is malleable and ductile. There are eight broad categories of use: batteries, petrol additives (no longer allowed in the EU), rolled and extruded products, alloys, pigments and compounds, cable sheathing, shot and ammunition.
Effects of Mercury on the environment
Mercury is a toxic substance which has no known function in human biochemistry or physiology and does not occur naturally in living organisms. Inorganic mercury poisoning is associated with tremors, gingivitis and/or minor psychological changes, together with spontaneous abortion and congenital malformation.
Monomethylmercury causes damage to the brain and the central nervous system, while foetal and postnatal exposure have given rise to abortion, congenital malformation and development changes in young children.
In what form is emitted Mercury?
Mercury is a global pollutant with complex and unusual chemical and physical properties. The major natural source of mercury is the degassing of the Earth’s crust, emissions from volcanoes and evaporation from natural bodies of water.
World-wide mining of the metal leads to indirect discharges into the atmosphere. The usage of mercury is widespread in industrial processes and in various products (e.g. batteries, lamps and thermometers). It is also widely used in dentistry as an amalgam for fillings and by the pharmaceutical industry. Concern over mercury in the environment arises from the extremely toxic forms in which mercury can occur.
Mercury is mostly present in the atmosphere in a relatively unreactive form as a gaseous element. The long atmospheric lifetime (of the order of 1 year) of its gaseous form means the emission, transport and deposition of mercury is a global issue.
Natural biological processes can cause methylated forms of mercury to form which bioaccumulate over a million-fold and concentrate in living organisms, especially fish. These forms of mercury: monomethylmercury and dimethylmercury are highly toxic, causing neurotoxicological disorders. The main pathway for mercury to humans is through the food chain and not by inhalation.
The main sources of mercury emissions in the UK are from the manufacture of chlorine in mercury cells, non-ferrous metal production, coal combustion and crematoria. UK emissions of mercury are uncertain and it is estimated that the range is from 13 to 36 tonnes per year (DERA). Emissions are estimated to have declined by around ѕ’s between 1970-1998 (NAEI), mainly due to improved controls on mercury cells and their replacement, and the fall in coal use.
Whilst there has been a decline in the level of European emissions of mercury, emissions from outside of Europe have started to increase – increasing the level of ambient concentrations in the continent.
Effects of Nickel on the environment
Small amounts of Nickel are needed by the human body to produce red blood cells, however, in excessive amounts, can become mildly toxic. Short-term overexposure to nickel is not known to cause any health problems, but long-term exposure can cause decreased body weight, heart and liver damage, and skin irritation. The EPA does not currently regulate nickel levels in drinking water. Nickel can accumulate in aquatic life, but its presence is not magnified along food chains.
Effects of Selenium on the environment
Selenium is needed by humans and other animals in small amounts, but in larger amounts can cause damage to the nervous system, fatigue, and irritability. Selenium accumulates in living tissue, causing high selenium content in fish and other organisms, and causing greater health problems in human over a lifetime of overexposure. These health problems include hair and fingernail loss, damage to kidney and liver tissue, damage to circulatory tissue, and more severe damage to the nervous system.
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